Peningkatan Efisiensi Poli Tanin Sebagai Dye Pada Dye Sensitized Solar Cell Menggunakan Crosslinker Glutaraldehyde

Hanifah Putri Indah Subriadi, Hardeli Hardeli

Abstract

Dye Sensitized Solar Cell (DSSC) is the latest generation of solar cells with dyes as absorbers of photons from sunlight. At this time, the DSSC efficiency obtained is still relatively low so that research on DSSC is still being developed to produce DSSC with higher efficiency. One of the methods used to increase the efficiency of DSSC is polymerization of dyes. Polymerization of dyes aims to increase conjugated double bonds. The more conjugated double bonds, the more photons will be absorbed so that more electrons will flow. In this study, tannins were used as dyes. In the tannin polymerization process, crosslinking agents are used to bind tannin monomers with other tannin monomers. the variable in this study was the volume of the glutaraldehyde crosslinking agent (1.5 mL, 2.5 mL, 3 mL). The results of this study obtained the highest DSSC efficiency of 12.20% at a volume of 2.5 mL of crosslinking agent.

Keywords

Crosslinker, DSSC, Efficiency, Poly-Tannin Acid

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References

I. Kholiq, “Analisis Pemanfaatan Sumber Daya Energi Alternatif Sebagai Energi Terbarukan untuk Mendukung Subtitusi BBM,” Jurnal Iptek, vol. 19, no. 2, pp. 75–91, 2015.

R. G. Lina and H. Hardeli, “Pengaruh KOH Sebagai Inisiator Pada Polimerisasi Tanin Terhadap Efisiensi Sel Surya DSSC,” Periodic, vol. 11, no. 1, pp. 40–44, 2022.

R. Andari, “Sintesis dan Karakterisasi Dye Sensitized Solar Cells (DSSC) dengan Sensitizer Antosianin dari Bunga Rosella,” JIIF (Jurnal Ilmu dan Inovasi Fisika), vol. 1, no. 2, pp. 140–150, 2017.

R. Damayanti, Hardeli, and H. Sanjaya, “Preparasi Dye Sensitized Solar Cell (DSSC) Menggunakan Ekstrak Antosianin Ubi Jalar Ungu (Ipomea batatas L.),” Jurnal Sains dan Teknologi, vol. 6, no. 2, 2014.

D. L. Pangestuti, G. Gunawan, and A. Haris, “Pembuatan Dye Sensitized Solar Cell (DSSC) dengan Sensitizer Antosianin dari Buah Buni (Antidesma bunius L),” Jurnal Kimia Sains dan Aplikasi, vol. 11, no. 3, 2008.

R. Sri Irianty and S. R. Yenti, “Pengaruh Perbandingan Pelarut Etanol-Air Terhadap Kadar Tanin Pada Sokletasi Daun Gambir (Uncaria gambir Roxb),” Sagu, vol. 13, no. 1, 2014.

T. S. Fangidae, T. M. P. B. Bage, A. A. Anggrowati, and Y. Sudaryanto, “Study of Malachite Green Adsorption using Tannin-Based Adsorbent (TBA) from Mangrove Bark (Rhizophora mucronata),” In Seminar Nasional Teknik Kimia Kejuangan, p. 9, 2020.

Y. C. Danarto, S. Ajie Prihananto, and Z. Anjas Pamungkas, “Pemanfaatan Tanin dari Kulit Kayu Bakau sebagai Pengganti Gugus Fenol pada Resin Fenol Formaldehid,” Prosiding Seminar Nasional Teknik Kimia “Kejuangan” 2011, 2011.

M. S. Alhumaimess et al., “Recyclable Glutaraldehyde Cross-linked Polymeric Tannin to Sequester Hexavalent Uranium from Aqueous Solution,” J Mol Liq, vol. 281, 2019.

R. T. Ako et al., “Evaluation of Surface Energy State Distribution and Bulk Defect Concentration in DSSC Photoanodes Based on Sn, Fe, and Cu Doped TiO2,” Appl Surf Sci, vol. 351, 2015.

Nuryetti, H. Hermansyah, and M. Nasikin, “Bionanokomposit: Peluang Polimer Alami Sebagai Material Baru Semikonduktor,” Riset Industri, vol. VI, no. I, 2012.

T. Varila, H. Romar, T. Luukkonen, T. Hilli, and U. Lassi, “Characterization of Lignin Enforced Tannin/Furanic Foams,” Heliyon, vol. 6, no. 1, 2020.

R. G. Lina and H. Hardeli, “Pengaruh KOH Sebagai Inisiator Pada Polimerisasi Tanin Terhadap Efisiensi Sel Surya DSSC,” Periodic, vol. 11, no. 1, 2022.

S. Chadijah, D. Dahlan, and H. Harmadi, “Pembuatan Counter Electrode Karbon Untuk Aplikasi Elektroda Dye-Sensitized Solar Cell (DSSC),” Jurnal Ilmu Fisika | Universitas Andalas, vol. 8, no. 2, 2017.

K. Z. Taqwa, “Studi Eksperimental Pengaruh Intensitas Cahaya Terhadap Performa DSSC (Dye Sensitized Solar Cell) Dengan Ekstrak Buah dan Sayur Sebagai Dye Sensitizer,” (Doctoral Dissertation, Institut Technology Sepuluh Nopember), 2015.

H. Sanjaya, “Degradasi Metil Violet Menggunakan Katalis ZnO-TiO2 Secara Fotosonolisis,” Eksakta: Berkala Ilmiah Bidang MIPA (E-ISSN: 2549-7464), vol. 19, no. 1, pp. 91–99, 2018.

R. N. Maurani, D. Purnamasari, and R. Zainul, “Preparation of TiO2 Thin Layer on Ceramics Using Dip Coating Method for Degradation Humic Acid,” in Journal of Physics: Conference Series, 2020.

F. N. Agdisti, L. Yunita, R. Luli, P. I. Novita, and Hardeli, “Peningkatan Performansi Dye Sensitized Solar Cell (DSSC) dengan Ekstrak Kulit Jengkol sebagai Zat Warna Melalui Elektrodeposisi Zn pada TiO2,” Paper Knowledge. Toward a Media History of Documents, vol. 3, no. 21, 2019.

R. Habibah, “Penentuan Berat Molekul dan Derajat Polimerisasi Α – Selulosa Yang Berasal dari Alang-Alang (Imperata Cylindrica) dengan Metode Viskositas,” Saintia Kimia, vol.1, 2013.

Wahyu. Hariyanto, Hariyanto & Tofa, Mus & Djafar, Zuryati & Piarah, “Mathematical Modeling in Combining Photovoltaic and Thermoelectric Generator using a Spectrum Splitter,” EPI International Journal of Engineering, vol. 2, pp. 74–79, 2019.

DOI: http://dx.doi.org/10.52759/reactor.v4i1.72

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