Pengaruh Variasi Waktu dan Kecepatan Pengadukan Terhadap Difusivitas dan Konstanta Reaksi Dengan Proses Ekstraksi Reaktif

Clarisa Hany Az Zahra, Mega Mustikaningrum, Fikrah Dian Indrawati Sawali, Pra Cipta Buana Wahyu Mustika

Abstract

The world is experiencing a crisis of scarcity of diesel fuel sources. The B30 program is to develop energy sources by utilizing alternative energy sources to prevent petroleum shortages. This program also supports research, namely making biodiesel using non-edible raw materials. Apart from that, another benefit of this research is to determine the effect of time on the yield of biodiesel production, knowing the effect of stirring speed on the diffusivity constant and reaction speed constant of the reactive extraction process. Biodiesel production in this research uses a reactive extraction process. The raw materials used are mahogany seeds, the solvent is methanol, chloroform as a co-solvent, and KOH as a catalyst. This process uses a temperature of 65°C, reaction time of 40 and 80 minutes, and varying stirring speeds of 200 and 300 rpm. The effect of time with a variable stirring speed of 200 rpm the longer the resulting yield increases, while at a stirring speed of 300 rpm the resulting yield decreases. The yield obtained at 200 rpm stirring was 82.363% (40 minutes), 87.6366% (80 minutes), 84.7605% (40 minutes), and 78.7204 (80 minutes). For the methyl ester diffusion constant, the stirring speed of 200 rpm is 8,20 x 10-8 dm2/minute, while the stirring speed of 300 rpm is 8,17 x 10-8 dm2/minute. The reaction rate constant is 1.99 dm3/mol min.

Keywords

Biodiesel, Diffusivity, Reactive Extraction, Reaction Rate Constant, Stirring Speed

Full Text:

PDF

References

N. F. Deli, M. A. Widiatma, E. Mei, K. Harga, and D. Terhadap, “Mengurangi Dampak Krisis Energi: Energi Terbarukan Tanggapan Masyarakat di Twitter Terhadap Kenaikan Harga BBM,” no. April, pp. 1–7, 2022.

W. Nurcholis et al., “The α-Glucosidase Inhibitory Activity of Seed Extract of Mahogany (Swietenia macrophylla King.),” Curr. Biochem. 2019, vol. 6, no. 1, pp. 35–44, 2019.

I. B. Rahardja, Sukarman, and A. I. Ramadhan, “Analisis Kalori Biodiesel Crude Palm Oil (CPO) Dengan Katalis Abu Tandan Kosong Kelapa Sawit (ATKKS),” J. UMJ, vol. 3, pp. 1–12, 2019.

U. Habibah, N. D. Putri, and A. S. Silitonga, “Inovasi Campuran Limbah Minyak Goreng (Waste Cooking Oil) Dan Minyak Jarak Pagar ( Jatrophacurcasoil) Sebagai Biodiesel Untuk Sektor,” pp. 1039–1046, 2022.

L. Nurliana, F. Kasman, and H. Ritonga, “Sintesis Metil Ester Sulfonat dari Minyak Mahoni (Switenia mahagoni Linn) Menggunakan Reagen Natrium Bisulfit,” J. Ilmi Kim., vol. 11, pp. 76–83, 2022.

Furqon, A. kelik Nugroho, and M. K. Anshorulloh, “Kajian Penggunaan Katalis KOH Pada Pembuatan Biodiesel Menggunakan Reverse Flow Biodiesel Secara Batch,” 2019.

M. E. Yulianto, R. Firyanto, M. F. S. Mulyaningsih, S. U. Handayani, and R. Amalia, “Pengaruh Kondisi Operasi Ekstraksi Reaktif Gelombang Mikro Untuk Produksi Biodisel Dari Biji Kemiri Sunan Secara In Situ,” Metana, vol. 12, no. 02, pp. 50–58, 2018.

E. D. Daryono, A. C. Rengga, and I. Safitri, “In Situ Transesterifikasi Minyak Biji Mahoni Menjadi Metil Ester Dengan Co-Solvent THF (Tetrahydrofuran),” Reakt. Vol. 15, vol. 15, no. 1, p. 51, Apr. 2014, doi: 10.14710/reaktor.15.1.51-58.

P. Novalina et al., “Pengaruh Variasi Variabel Reaksi Pada Proses Ekstraksi,” vol. 4, no. 4, pp. 18–24, 2020.

A. Kurniawati, “Pengaruh Jenis Pelarut Pada Proses Ekstraksi Bunga Mawar Dengan Metode Maserasi Sebagai Aroma Parfum,” J. Creat. Student, vol. 2, no. 2, pp. 74–83, 2017, doi: 10.15294/jcs.v2i2.14587.

E. Asniwarsih, “Uji Aktivasi Antioksidan Daun Mangrove Pidada Merah (Sonneratioa Caseolaris) Dan Pidada Putih (Sonneratia alba),” no. 2504, pp. 1–9, 2021, [Online]. Available: http://repository.akfarsurabaya.ac.id/id/eprint/590%0A

E. Megawati, A. Adriansyah, A. Mukimin, D. Ariyani, Yuniarti, and M. Lutfi, “Analisis Sifat Fisika dan Nilai Keekonomian Minyak Goreng Bekas Menjadi Biodiesel dengan Metode Transesterifikasi,” vol. 9, no. 1, 2022.

M. Busyairi, A. Z. Muttaqin, I. Meicahyanti, and S. Saryadi, “Potensi Minyak Jelantah Sebagai Biodiesel dan Pengaruh Katalis Serta Waktu Reaksi Terhadap Kualitas Biodiesel Melalui Proses Transesterifikasi,” J. Serambi Eng., vol. 5, no. 2, pp. 933–940, 2020, doi: 10.32672/jse.v5i2.1920.

Sulistianingsih and D. Wahyuningtyas, “Optimasi Pembuatan Biodiesel Dari Minyak Jelantah Dengan Katalisator Kalisum Oksida (CaO) Dengan Proses Metanolisis (Variabel Suhu Reaksi),” Inov. Porses, vol. 4, no. 1, pp. 81–87, 2019, [Online]. Available: https://journal.akprind.ac.id/index.php/JIP/article/view/2119

Q. Aeni, “Analisis Timbulan Minyak Jelantah dari Rumah Makan di Kawasan Kuliner Alun-Alun Kecamatan Kendal,” skripsi Univ. Islam Indonesia, pp. 5–13, 2020.

Refbacks

  • There are currently no refbacks.